Potential difference and electromotive force (EMF) are both concepts related to electricity, but they have distinct meanings and applications. Let's compare and contrast them:
Definition:
Potential Difference: Also known as voltage, potential difference is the difference in electric potential energy per unit charge between two points in an electric field. It measures the work done to move a unit positive charge from one point to another in the electric field. The unit of potential difference is the volt (V).
Electromotive Force (EMF): EMF is the total energy supplied by a source (like a battery or a generator) to a unit positive charge as it completes a circuit. EMF represents the maximum potential difference across the terminals of the source when it is not connected to any load. The unit of EMF is also the volt (V).
Role in Circuits:
Potential Difference: In a circuit, potential difference is responsible for the flow of electric charge (current) from one point to another. It is the driving force that pushes electrons through the circuit elements like resistors, capacitors, and inductors.
Electromotive Force (EMF): EMF is the force that causes charges to flow in a closed circuit when it is connected to a load. It provides the energy required to maintain the current flow in the circuit. EMF is the voltage provided by the source, while potential difference is the voltage across individual circuit elements.
Origin:
Potential Difference: It occurs due to the presence of an electric field created by charges in the circuit or between two points with different potentials.
Electromotive Force (EMF): EMF is generated by a device like a battery or a generator that converts other forms of energy (chemical, mechanical, etc.) into electrical energy, creating a potential difference between its terminals.
Direction of Flow:
Potential Difference: It exists between any two points in an electric field, and the direction of the potential difference is from the higher potential to the lower potential.
Electromotive Force (EMF): EMF represents the potential difference across the terminals of the source, and its direction is from the negative terminal to the positive terminal within the source.
In an Open Circuit:
Potential Difference: In an open circuit (a circuit with a gap), potential difference exists across the gap but no current flows.
Electromotive Force (EMF): In an open circuit, EMF can still be measured across the terminals of the source as it represents the total energy supplied by the source.
In summary, potential difference represents the voltage between any two points in an electric field, while electromotive force (EMF) is the voltage provided by a source. Potential difference is responsible for driving current through the circuit elements, while EMF provides the energy for maintaining the current flow when the circuit is connected to a load.