Doped semiconductors are a fundamental concept in semiconductor physics and technology. Semiconductors are materials that have electrical conductivity between that of insulators (materials that don't conduct electricity well) and conductors (materials that conduct electricity well). The conductivity of semiconductors can be modified by introducing impurities into their crystal structure through a process called "doping."
Doping involves intentionally adding small amounts of certain atoms, known as dopants, to the semiconductor crystal lattice. These dopants can be of two types:
Donor Dopants: Donor dopants introduce extra electrons into the semiconductor's conduction band, making it easier for the material to conduct electricity. Common donor dopants include elements from Group V of the periodic table, such as phosphorus or arsenic. Since these elements have one more valence electron than the semiconductor's host material (e.g., silicon), they contribute an excess electron that can move through the crystal lattice and participate in electrical conduction.
Acceptor Dopants: Acceptor dopants create "holes" in the valence band of the semiconductor, which behave like positive charge carriers. These holes can move through the lattice in a manner similar to electrons. Common acceptor dopants include elements from Group III, such as boron or gallium. These elements have one less valence electron than the host semiconductor, creating a vacancy in the crystal lattice that can attract and conduct positive charge.
Doping can significantly alter the electrical properties of a semiconductor material. When a semiconductor is doped, it becomes an "n-type" or a "p-type" semiconductor, depending on the type of dopants introduced:
n-type Semiconductor: When donor dopants are added to a semiconductor material, it becomes an n-type semiconductor. These extra electrons introduced by the donors increase the concentration of free electrons available for conduction, making the material more conductive. Electrons are the majority charge carriers in n-type semiconductors.
p-type Semiconductor: When acceptor dopants are added to a semiconductor material, it becomes a p-type semiconductor. The acceptor dopants create holes in the crystal lattice, which can move and behave like positive charge carriers. Holes are the majority charge carriers in p-type semiconductors.
Doped semiconductors are the building blocks of various electronic devices, including diodes, transistors, and integrated circuits. By controlling the type and concentration of dopants, engineers can design semiconductors with specific electrical properties, enabling the creation of functional electronic components and enabling the manipulation of current flow in semiconductor devices. This manipulation of electrical properties through doping is at the core of modern electronics and technology.