A supercapacitor-based energy storage system, also known as an ultracapacitor or electric double-layer capacitor (EDLC), functions by storing electrical energy in an electric field between two closely spaced electrodes with a high surface area and an electrolyte. Unlike conventional batteries, which store energy through chemical reactions, supercapacitors store energy electrostatically.
Here's how a supercapacitor-based energy storage system typically works:
Electrodes: The supercapacitor consists of two electrodes made of a highly porous material with an extremely high surface area, such as activated carbon or graphene. This large surface area allows more ions to be stored and increases the capacitance of the device.
Separator: A separator is placed between the two electrodes to prevent direct contact and short circuits while allowing the electrolyte to permeate through the electrode's porous structure.
Electrolyte: The electrolyte is the medium that allows ions to move between the two electrodes. It is usually an ionic liquid or an aqueous solution containing positive and negative ions. When a voltage is applied, ions in the electrolyte are attracted to the oppositely charged electrodes, storing energy in the form of an electric field.
Charging: To store energy in the supercapacitor, a voltage is applied across the two electrodes. Positive ions are attracted to the negative electrode, and negative ions are attracted to the positive electrode. This process accumulates electric charges on the electrode surfaces.
Discharging: When the supercapacitor is connected to an external circuit (e.g., a load), the stored energy is released as a rapid discharge of current. Since the energy is stored electrostatically, the discharge process can occur very quickly, making supercapacitors excellent for applications that require rapid bursts of power.
Cycling: Supercapacitors can undergo numerous charge and discharge cycles without significant degradation. This cycling ability is one of their advantages over traditional batteries, which tend to degrade over time due to chemical reactions.
Supercapacitors are well-suited for applications that require high power and fast charge/discharge cycles. However, they have a lower energy density compared to batteries, which means they cannot store as much energy for longer durations. As a result, supercapacitors are often used in combination with batteries or other energy storage systems to provide a balance between high power and energy storage capabilities.