The thermoelectric effect is a phenomenon in which a temperature gradient within a conductor (or a semiconductor) leads to the generation of an electric voltage or potential difference. This effect arises due to the interaction between heat flow and electric charge carriers (usually electrons) within the material. It's a manifestation of the fundamental principles of thermodynamics and the behavior of charge carriers in conductive materials.
There are two primary types of thermoelectric effects: the Seebeck effect and the Peltier effect.
Seebeck Effect:
The Seebeck effect, also known as the thermoelectric or thermoelectromotive force, occurs when two points in a conductor or a circuit are at different temperatures. The temperature gradient causes the charge carriers (electrons) to move from the hotter region to the cooler region, creating an imbalance in charge distribution. This migration of charges generates an electric potential difference between the two ends of the conductor. This potential difference can be measured as a voltage, and if the circuit is closed, a current will flow through it.
Peltier Effect:
The Peltier effect is the reverse process of the Seebeck effect. When an electric current passes through a junction of two dissimilar conductors or semiconductors (called a thermoelectric junction), heat is either absorbed or released at the junction. If the current flows from the colder region to the hotter region, heat is absorbed, leading to a cooling effect. Conversely, if the current flows from the hotter region to the colder region, heat is released, resulting in a heating effect.
These two effects are closely related and are often utilized in various practical applications. One notable application is thermoelectric generators, which convert waste heat (from industrial processes or vehicle engines) into usable electrical energy. Another application is in thermoelectric coolers, where the Peltier effect is used to create localized cooling or heating by controlling the direction of electric current across a thermoelectric junction.
The efficiency of thermoelectric devices is determined by the material's thermoelectric properties, which include its Seebeck coefficient (the voltage generated per unit temperature difference), electrical conductivity, and thermal conductivity. Researchers are constantly working on improving the efficiency of thermoelectric materials to make them more viable for energy harvesting and cooling applications.