The conductivity of a conductor refers to its ability to conduct electrical current. Temperature has a significant impact on the conductivity of a conductor, and this relationship is often described by the concept of "temperature coefficient of resistance."
In most cases, as the temperature of a conductor increases:
Metals: The conductivity generally decreases. This is because at higher temperatures, the atoms in the metal lattice vibrate more vigorously, disrupting the flow of electrons, which results in increased resistance to the flow of electrical current. The degree to which the conductivity decreases depends on the specific material.
Semiconductors: The conductivity typically increases. In semiconductors, the behavior is more complex. At higher temperatures, some electrons can gain enough energy to move from the valence band to the conduction band, creating more charge carriers (free electrons and holes), which increases conductivity. However, the relationship between temperature and conductivity in semiconductors can vary based on the material type and doping level.
Insulators: The conductivity can increase slightly. In insulators, which have very few free charge carriers at any temperature, a slight increase in temperature can cause a small increase in conductivity due to the breaking of some covalent bonds, which can release charge carriers.
To quantify the effect of temperature on conductivity, the temperature coefficient of resistance (TCR) is often used. It's defined as the change in resistance of a material per degree Celsius change in temperature. The TCR can be expressed as a percentage change in resistance per degree Celsius:
TCR (%) = [(Rt - Ro) / Ro] * 100 / (Tt - To)
Where:
Rt = Resistance at temperature Tt
Ro = Resistance at temperature To
Tt = Final temperature
To = Initial temperature
Different materials have different temperature coefficients of resistance, and this coefficient helps engineers and scientists predict how the conductivity of a material will change with temperature.
In summary, the relationship between temperature and conductivity varies depending on the type of material. For metals, increased temperature generally leads to decreased conductivity, while for semiconductors, it often leads to increased conductivity. For insulators, there might be a small increase in conductivity with temperature. The temperature coefficient of resistance provides a quantitative way to understand and predict these changes.