In the context of basic electricity, the concept of "free electrons" refers to electrons that are not bound to atoms and are therefore able to move freely within a material. This movement of free electrons is what gives rise to electric current.
In most materials, the outermost shell of an atom's electrons, known as the valence shell, contains electrons that are relatively loosely bound to the nucleus. When an external electric force is applied to a material, such as when a voltage is applied across it, these loosely bound electrons can become detached from their parent atoms and move through the material. These detached electrons are referred to as free electrons.
Metals are particularly good conductors of electricity because they have a high concentration of free electrons. The electrons in the outer shells of metal atoms are only weakly attracted to the positively charged atomic nuclei, allowing them to move relatively easily throughout the material in response to an applied voltage. This is why metals are used for conducting electricity in wires and other components of electrical circuits.
Non-conductive materials, also known as insulators, have electrons that are more tightly bound to their atoms, making it difficult for them to move freely. In these materials, the movement of electrons is limited, and they don't contribute significantly to electric current.
Semiconductors are a special class of materials that have properties between conductors and insulators. At certain conditions, they can behave as conductors by allowing a controlled flow of electrons. The conductivity of semiconductors can be altered through various methods, like doping, to make them suitable for various electronic applications, including transistors and diodes.
In summary, free electrons are crucial for the flow of electric current through conductive materials, such as metals. Their ability to move in response to an applied electric field is what allows electricity to be transmitted and utilized in various electrical and electronic devices.