Piezoelectric materials generate electrical charges through the piezoelectric effect, which is a unique property exhibited by certain materials. The word "piezoelectric" comes from the Greek word "piezein," meaning to press or squeeze. When mechanical stress or pressure is applied to a piezoelectric material, it undergoes a change in shape or size, resulting in the generation of an electric charge.
The piezoelectric effect occurs due to the arrangement of atoms or molecules within the crystal structure of the material. Piezoelectric materials have a non-centrosymmetric crystal structure, meaning the positive and negative charges within the unit cell are not symmetrically distributed. This lack of symmetry is crucial for the piezoelectric effect to take place.
Here's a step-by-step explanation of how the piezoelectric effect works:
Initial state: In the absence of any external forces or stresses, the positive and negative charges within the piezoelectric material are balanced, and there is no net electric charge or polarization.
Mechanical stress application: When mechanical stress or pressure is applied to the material, it causes the positive and negative charges to shift slightly within the crystal lattice. This deformation can be due to stretching, compression, bending, or any other mechanical force.
Charge separation: As the crystal lattice deforms, the positive and negative charges become asymmetrically distributed, leading to the separation of charge centers within the material.
Electric polarization: The separation of charge creates an internal electric dipole moment within the material. The dipole moment is a vector pointing from the negative to the positive charge center.
Electric charge generation: Due to the internal dipole moment, an electric field is produced within the material, resulting in the generation of a net electric charge on the surface of the material. One side of the material becomes positively charged, while the other side becomes negatively charged.
Reversibility: The piezoelectric effect is reversible. If the mechanical stress is removed, the material will return to its original shape, and the internal charge separation will disappear.
Piezoelectric materials find various applications in sensors, actuators, transducers, and even energy harvesting devices. Common examples of piezoelectric materials include quartz, lead zirconate titanate (PZT), and certain ceramics. The piezoelectric effect plays a crucial role in the functionality of devices like piezoelectric sensors in microphones, ultrasound transducers, and even piezoelectric igniters in gas lighters.