Fuel cells generate electricity through electrochemical reactions by converting the chemical energy stored in a fuel directly into electrical energy. The main components of a fuel cell are the anode, the cathode, and an electrolyte. The most common type of fuel cell, known as the Proton Exchange Membrane (PEM) fuel cell, will be used as an example here.
Anode: At the anode of the fuel cell, hydrogen gas (H2) is fed into the cell. A catalyst, typically made of platinum, helps split the hydrogen molecules into positively charged hydrogen ions (protons) and negatively charged electrons. This process is known as oxidation:
H2 (hydrogen) → 2H+ (protons) + 2e- (electrons)
Electrolyte: The protons generated at the anode are free to move through the electrolyte. The electrolyte is a special membrane that allows only positively charged ions (in this case, protons) to pass through while blocking the electrons.
Cathode: At the cathode, oxygen gas (O2) from the air is introduced, and it reacts with the protons and electrons that have traveled through the electrolyte to form water (H2O). This process is known as reduction:
2H+ (protons) + 2e- (electrons) + O2 (oxygen) → H2O (water)
Electrical Circuit: As the electrons are not allowed to pass through the electrolyte directly, they have to flow through an external circuit from the anode to the cathode. This external circuit forms the electrical load and is where the electrical energy is harvested for use.
Electrical Energy: The flow of electrons through the external circuit creates an electric current, which can be utilized to power electrical devices and perform work.
Overall, the chemical reactions at the anode and cathode sides of the fuel cell create a flow of electrons, which results in the production of electricity. The only byproducts of this process are water and heat, making fuel cells an environmentally friendly and efficient way to generate electricity, especially when using hydrogen as the fuel source.