A thermophotovoltaic (TPV) cell is a type of photovoltaic device that converts heat radiation (thermal energy in the form of photons) into electricity using the principles of the photovoltaic effect. The photovoltaic effect is the phenomenon where certain materials, called semiconductors, can generate an electric current when exposed to light. Here's how a thermophotovoltaic cell works:
Heat Source: The process begins with a heat source. This heat source can be any object emitting heat radiation in the form of photons. Common heat sources include a combustion flame, a hot filament, or any material at an elevated temperature.
Emission of Photons: The heat source emits photons as a result of its temperature. These photons carry energy corresponding to the temperature of the source. The wavelength distribution of these emitted photons is determined by the source's temperature.
Selective Absorption: The TPV cell contains a semiconductor material that has specific energy bandgaps designed to match the energy levels of the incoming photons. These bandgaps determine which photons can be absorbed by the semiconductor material. The goal is to select a bandgap that allows the cell to absorb a significant portion of the incoming photons' energy.
Photon Absorption: When the photons from the heat source strike the semiconductor material in the TPV cell, they can be absorbed by the material if their energy matches the material's bandgap. This absorption causes electrons in the semiconductor to be excited from their lower energy states to higher energy states.
Generation of Electron-Hole Pairs: The absorption of photons creates electron-hole pairs in the semiconductor material. Electrons are excited to higher energy levels (conduction band), leaving behind positively charged "holes" in the lower energy levels (valence band).
Electric Current Generation: The separation of electron-hole pairs creates a charge imbalance within the semiconductor material. This imbalance creates an electric field, and if the semiconductor material is appropriately designed, it can result in the movement of electrons towards the higher potential side and holes towards the lower potential side. This movement of charge carriers constitutes an electric current.
Extraction of Electricity: The generated electric current can be extracted from the TPV cell through external electrical contacts. By connecting the TPV cell to an external circuit, the electric current can be used to power devices or be stored in batteries.
It's important to note that TPV cells have specific design considerations, such as selecting the right semiconductor material, optimizing the energy bandgap, and managing heat losses to enhance their efficiency. The efficiency of TPV cells is influenced by factors like the match between the emission spectrum of the heat source and the absorption characteristics of the semiconductor material. While TPV technology holds promise for converting heat radiation into electricity, challenges remain in terms of achieving high efficiency and cost-effectiveness.