In fuel cells, electrical energy is converted into chemical energy through an electrochemical reaction. The process involves the conversion of the chemical energy stored in a fuel, typically hydrogen or a hydrocarbon-based fuel like methane, into electrical energy.
Here's a general overview of how electrical energy is converted into chemical energy in a fuel cell:
Fuel Supply: Hydrogen gas or a hydrocarbon fuel (e.g., methane) is supplied to the anode of the fuel cell.
Anode Reaction: At the anode, the fuel undergoes a chemical reaction, typically oxidation. In the case of hydrogen fuel cells, hydrogen molecules (H2) dissociate into protons (H+) and electrons (e-).
Anode Reaction (Hydrogen Fuel Cell):
H2 → 2H+ + 2e-
Electrolyte: The fuel cell contains an electrolyte, which is a special material that allows the passage of ions (charged particles) between the anode and cathode but restricts the flow of electrons. Commonly used electrolytes include proton exchange membrane (PEM), alkaline, solid oxide, and molten carbonate.
Proton Exchange Membrane (PEM) Fuel Cell: In PEM fuel cells, a proton-conducting polymer membrane separates the anode and cathode compartments, allowing only protons to pass through.
Cathode Reaction: Oxygen gas (O2) from the air is supplied to the cathode of the fuel cell. At the cathode, oxygen molecules and electrons react to form oxide ions.
Cathode Reaction:
O2 + 4e- + 4H+ → 2H2O
Electrochemical Reaction: The electrons generated at the anode cannot pass through the electrolyte, so they are forced to travel through an external electrical circuit, creating an electrical current. This flow of electrons through the circuit can be harnessed to do work, such as powering electrical devices.
Electrical Energy Output: The electrons arriving at the cathode combine with oxygen and protons (which have traveled through the electrolyte) to produce water (H2O) as a byproduct. This reaction releases energy, which is in the form of chemical energy, as the final result.
Overall, the chemical energy in the fuel (hydrogen or hydrocarbon) is converted into electrical energy as the electrons travel from the anode to the cathode through an external circuit. This electrochemical process allows fuel cells to generate electricity in an efficient and environmentally friendly manner, with water as the primary emission.