A thermocouple generates electricity from temperature differences through a phenomenon known as the Seebeck effect. The Seebeck effect is a thermoelectric phenomenon in which a temperature gradient between two different types of metals or semiconductors results in the generation of an electric voltage.
Here's how the process works:
Dissimilar Materials: A thermocouple consists of two wires made of different metals or semiconductor materials. These materials are chosen based on their differing thermoelectric properties. One wire is usually referred to as the "hot" or measuring junction, while the other is the "cold" or reference junction.
Temperature Gradient: When there is a temperature difference between the two junctions of the thermocouple, a temperature gradient is established along the length of the wires. This means that one end of the thermocouple is at a higher temperature (hot junction) and the other end is at a lower temperature (cold junction).
Electron Movement: Each metal or semiconductor has a different arrangement of electrons in their atomic structure. When the temperature gradient is applied, electrons in the hotter metal gain more energy and become more agitated, causing them to move from the hot junction towards the cold junction. This movement of electrons creates a flow of electric current.
Voltage Generation: The movement of electrons due to the temperature difference creates a voltage difference between the two ends of the thermocouple. This voltage difference is known as the thermoelectric voltage or Seebeck voltage. It's essentially a measure of the temperature difference between the two junctions.
Measurement: By connecting the two ends of the thermocouple to a circuit, the generated voltage can be measured and used as an indicator of the temperature difference between the two junctions. This is the basis for temperature measurement using thermocouples.
It's important to note that the voltage generated by a single thermocouple is usually quite small. To generate a usable amount of electrical power, multiple thermocouples can be connected in series or parallel to create a thermoelectric module or thermoelectric generator (TEG). These TEGs find applications in various fields, such as power generation from waste heat, remote sensing, and temperature measurement in industrial and scientific settings. The efficiency of thermocouples and TEGs depends on the choice of materials, temperature gradient, and the design of the system.