A thermoelectric generator (TEG) is a solid-state device that converts heat directly into electricity through the Seebeck effect, discovered by Thomas Johann Seebeck in 1821. The Seebeck effect states that when a temperature gradient exists between two different materials, an electric voltage is generated.
The basic components of a thermoelectric generator are thermoelectric materials (also known as thermoelectric modules or TE elements) and heat exchangers.
Here's how a thermoelectric generator operates:
Temperature Gradient: The fundamental principle behind a TEG is the existence of a temperature gradient across the device. This means that one side of the TEG is exposed to a heat source (hot side), while the other side is in contact with a heat sink (cold side). The greater the temperature difference between the two sides, the more efficient the TEG will be in generating electricity.
Thermoelectric Materials: The TEG contains thermoelectric materials, typically made from semiconductor materials, which have the unique property of being able to generate an electric potential when subjected to a temperature difference. Commonly used materials include bismuth telluride (Bi2Te3), lead telluride (PbTe), and silicon-germanium (SiGe) alloys. These materials have high thermoelectric efficiency, meaning they can efficiently convert heat into electricity.
Seebeck Effect: When there's a temperature gradient across the thermoelectric materials, a flow of charge carriers (electrons or holes) occurs from the hot side to the cold side. This results in the accumulation of positive and negative charges on each side, creating a potential difference (voltage) between the two sides. This is known as the Seebeck effect.
Electrical Circuit: To harvest the electricity generated by the TEG, an external electrical circuit is connected to the thermoelectric materials. This circuit typically consists of conductive wires or metal plates that connect the hot and cold sides of the TEG. The potential difference between the two sides creates an electric current to flow through the circuit when it is closed.
Power Output: The amount of electricity generated by the TEG depends on several factors, including the temperature difference between the hot and cold sides, the thermoelectric material's properties, and the size and design of the TEG. While the conversion efficiency of TEGs is generally lower compared to other power generation methods, they have unique applications in situations where waste heat or temperature differences are present, such as in industrial processes, automotive waste heat recovery, or remote power generation.
Overall, thermoelectric generators offer a reliable and solid-state way of converting heat directly into electricity, making them valuable in various applications, especially in scenarios where traditional power generation methods are impractical or inefficient.