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How does a fuel cell generate electricity through electrochemical reactions?

1 Answer

A fuel cell generates electricity through electrochemical reactions by converting the chemical energy stored in a fuel directly into electrical energy. The process involves two key components: an anode and a cathode separated by an electrolyte. The most common type of fuel cell is the proton exchange membrane fuel cell (PEMFC), which operates at relatively low temperatures and is widely used in various applications, including automotive and stationary power generation.

Here's a step-by-step explanation of how a fuel cell works:

Fuel Supply: Hydrogen gas (H2) is the most commonly used fuel for fuel cells. The hydrogen can be obtained from various sources, such as natural gas, methanol, ethanol, or pure hydrogen.

Anode Reaction: At the anode (the negative electrode), hydrogen molecules are split into protons (H+) and electrons (e-). The reaction that occurs at the anode is typically as follows:

H2 (hydrogen) → 2H+ (protons) + 2e- (electrons)

Electrolyte: The protons generated at the anode can move through the electrolyte, which is typically a polymer membrane that selectively allows protons to pass through while blocking electrons.

Cathode Reaction: At the cathode (the positive electrode), oxygen (from the air) reacts with the protons and electrons from the external circuit to form water. The overall reaction at the cathode is typically as follows:

2H+ (protons) + 1/2O2 (oxygen) + 2e- (electrons) → H2O (water)

External Circuit: The electrons produced in the anode reaction cannot pass through the electrolyte, so they are forced to travel through an external circuit (such as a wire) to reach the cathode, creating an electrical current in the process.

Electrical Output: The electrons traveling through the external circuit can be harnessed to perform useful work, such as powering an electric motor or charging a battery.

Water and Heat: The only byproducts of the overall fuel cell reaction are water and heat. The water vapor can be expelled from the fuel cell, and the heat generated can be captured and used for various purposes.

Fuel cells offer several advantages over traditional combustion engines, such as higher efficiency, reduced emissions (since the only byproduct is water), and quieter operation. They are increasingly being adopted as a clean and sustainable energy source in various applications.
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